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Hollow carbon spheres and their noble metal-free hybrids in catalysis

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1380-1407 doi: 10.1007/s11705-021-2097-z

Abstract: Herein, we overview hollow carbon sphere-based materials and their noble metal-free hybrids in catalysison controlling pore structure and surface morphology, and then heterogeneous doping as well as their metal-free/containing hybrids are presented; next, possible applications for non-noble metal/hollow carbon sphere

Keywords： hollow carbon spheres     functionalization     noble metal-free     catalysis    

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Copper nanoparticles/polyaniline-derived mesoporous carbon electrocatalysts for hydrazine oxidation

Tao Zhang, Tewodros Asefa

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 329-338 doi: 10.1007/s11705-018-1741-8

Abstract:

Copper nanoparticles-decorated polyaniline-derived mesoporous carbon that can serve as noble metal-freeelectrocatalyst for the hydrazine oxidation reaction (HzOR) is synthesized via a facile synthetic routeIts good electrocatalytic performance makes this material a promising alternative to conventional noblemetal-based catalysts (e.g., Pt) that are commonly used in HzOR-based fuel cells.

Keywords： copper nanoparticles     mesoporous carbon     noble metal-free electrocatalyst     hydrazine oxidation reaction    

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Recent advances on metal-free graphene-based catalysts for the production of industrial chemicals

Zhiyong Wang, Yuan Pu, Dan Wang, Jie-Xin Wang, Jian-Feng Chen

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 4,   Pages 855-866 doi: 10.1007/s11705-018-1722-y

Abstract: With the development of carbon catalysts, graphene-based metal-free catalysts have drawn increasing attentionIn recent years, the catalytic activities of metal-free catalysts have significantly improved and theyhave become promising alternatives to traditional metal-based catalysts.The use of metal-free catalysts greatly improves the sustainability of chemical processes.In view of this, the recent progress in the preparation of graphene-based metal-free catalysts along

Keywords： graphene-based materials     metal-free catalyst     industrial chemical productions     catalytic reaction    

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Metal-free, carbon-based catalysts for oxygen reduction reactions

Zhiyi Wu,Zafar Iqbal,Xianqin Wang

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 3,   Pages 280-294 doi: 10.1007/s11705-015-1524-4

Abstract: Developing metal-free, carbon-based catalysts to replace platinum-based catalysts for oxygen reduction

Keywords： oxygen reduction reaction     electrocatalysis     metal-free     carbon-based     polynitrogen    

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Noble-metal-free cobalt hydroxide nanosheets for efficient electrocatalytic oxidation

Jie Lan, Daizong Qi, Jie Song, Peng Liu, Yi Liu, Yun-Xiang Pan

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 948-955 doi: 10.1007/s11705-020-1920-2

Abstract: Cobalt hydroxide has been emerging as a promising catalyst for the electrocatalytic oxidation reactions, including the oxygen evolution reaction (OER) and glucose oxidation reaction (GOR). Herein, we prepared cobalt hydroxide nanoparticles (CoHP) and cobalt hydroxide nanosheets (CoHS) on nickel foam. In the electrocatalytic OER, CoHS shows an overpotential of 306 mV at a current density of 10 mA·cm . This is enhanced as compared with that of CoHP (367 mV at 10 mA·cm ). In addition, CoHS also exhibits an improved performance in the electrocatalytic GOR. The improved electrocatalytic performance of CoHS could be due to the higher ability of the two-dimensional nanosheets on CoHS in electron transfer. These results are useful for fabricating efficient catalysts for electrocatalytic oxidation reactions.

Keywords： electrocatalytic oxidation     cobalt hydroxide     nanosheet     water     glucose    

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Nitrogen-Doped Graphene Foam as a Metal-Free Catalyst for Reduction Reactions under a High Gravity Field Article

Zhiyong Wang, Zhijian Zhao, Jesse Baucom, Dan Wang, Liming Dai, Jian-Feng Chen

Engineering 2020, Volume 6, Issue 6,   Pages 680-687 doi: 10.1016/j.eng.2019.12.018

Abstract:

Herein, we report on the effect of a high gravity field on metal-free catalytic reduction, takinghighgravity rotating tube reactor packed with three-dimensional (3D) nitrogen-doped graphene foam (NGF) as a metal-freeThe apparent rate constant (kapp) of the metal-free catalytic reduction of NB inThe structure of the 3D metal-free catalysts was stable during the reaction process under a high gravitythe potential to use a high-gravity rotating packed tube reactor for the process intensification of metal-free

Keywords： High-gravity technology     Process intensification     Metal-free catalysts     Carbon nanomaterials     Catalytic    

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Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1986-2000 doi: 10.1007/s11705-023-2337-5

Abstract: On the active metal nanoparticle scale, the role of catalyst size in C–N bond cleavage has not been clearly

Keywords： sp3/sp2-hybridized C–N bond     noble metal nanoparticle     catalytic active site     turnover    

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Shape/size controlling syntheses, properties and applications of two-dimensional noble metal nanocrystals

Baozhen An,Mingjie Li,Jialin Wang,Chaoxu Li

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 3,   Pages 360-382 doi: 10.1007/s11705-016-1576-0

Abstract: Two dimensional (2D) nanocrystals of noble metals (e.g., Au, Ag, Pt) often have unique structural anddiscovering the fundamental mechanisms which govern the synthesis of the diverse geometries of these 2D metalreview, a brief historical survey of the intrinsic anisotropic properties and quantum size effects of 2D noblemetal nanocrystals is given and then a summary of synthetic approaches to control their shapes and sizes

Keywords： two-dimension     noble metal     nanocrystal     surface plasmon     controllable synthesis    

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Catalytic activity of noble metal nanoparticles toward hydrodechlorination: influence of catalyst electronic

Man ZHANG,Feng HE,Dongye ZHAO

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5,   Pages 888-896 doi: 10.1007/s11783-015-0774-1

Abstract: These metal nanoparticles were then tested for catalytic hydrodechlorination toward two classes of organochlorinatedat the Fermi level) of the metals, suggesting that adsorption of organochlorinated reactants on the metalPCE correlated with the adsorption energies of their molecular (non-dissociative) adsorption on the noble

Keywords： catalytic hydrodechlorination     electronic structure     metal nanoparticles     reaction mechanisms    

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Sulfur-deficient CoNi2S4 nanoparticles-anchored porous carbon nanofibers as bifunctional electrocatalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1707-1717 doi: 10.1007/s11705-023-2308-x

Abstract: carbon nanofibers-coupled CoNi2S4 nanoparticles are prepared as bifunctional electrocatalyst

Keywords： nanoparticle     sulfur vacancy     porous carbon nanofiber     transition metal sulfides     electrolysis    

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Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1487-1499 doi: 10.1007/s11705-021-2085-3

Abstract: Developing cost-effective electrocatalysts for oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is vital in energy conversion and storage applications. Herein, we report a simple method for the synthesis of graphene-reinforced CoS/C nanocomposites and the evaluation of their electrocatalytic performance for typical electrocatalytic reactions. Nanocomposites of CoS embedded in N, S co-doped porous carbon and graphene (CoS@C/Graphene) were generated via simultaneous sulfurization and carbonization of one-pot synthesized graphite oxide-ZIF-67 precursors. The obtained CoS@C/Graphene nanocomposites were characterized by X-ray diffraction, Raman spectroscopy, thermogravimetric analysis-mass spectroscopy, scanning electronic microscopy, transmission electronic microscopy, X-ray photoelectron spectroscopy and gas sorption. It is found that CoS nanoparticles homogenously dispersed in the in situ formed N, S co-doped porous carbon/graphene matrix. The CoS@C/10Graphene composite not only shows excellent electrocatalytic activity toward ORR with high onset potential of 0.89 V, four-electron pathway and superior durability of maintaining 98% of current after continuously running for around 5 h, but also exhibits good performance for OER and HER, due to the improved electrical conductivity, increased catalytic active sites and connectivity between the electrocatalytic active CoS and the carbon matrix. This work offers a new approach for the development of novel multifunctional nanocomposites for the next generation of energy conversion and storage applications.

Keywords： MOF derivative     graphene     electrocatalyst     oxygen reduction reaction     oxygen evolution reaction     hydrogen    

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Zinc modification of Ni-Ti as efficient NiZnTi catalysts with both geometric and electronic improvements for hydrogenation of nitroaromatics

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 4,   Pages 461-474 doi: 10.1007/s11705-021-2072-8

Abstract: nitroaromatics is an environmentally friendly technology for aniline production, and it is crucial to develop noble-metal-freeThese findings provide a rational strategy for the development of highly active non-noble-metal hydrogenation

Keywords： bimetal strategy     oxygen vacancy     non-noble metal catalyst     hydrogenation     aromatic nitro compounds    

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Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells

Gang WU

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 286-298 doi: 10.1007/s11708-017-0477-3

Abstract: To significantly reduce the cost of proton exchange membrane fuel cells, platinum-group metal (PGM)-freeThe current Edisonian approach (i.e., trial and error) to developing PGM-free catalysts has been ineffectiveStructural and chemical controlled precursors such as metal-organic frameworks are highly desirable for

Keywords： oxygen reduction     fuel cells     cathode     nonprecious metal catalysts     carbon nanocomposites    

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Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reduction and oxygen evolution reaction: a density functional theory study

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 5,   Pages 570-580 doi: 10.1007/s11705-022-2247-y

Abstract: Recently, metal–organic frameworks are one of the potential catalytic materials for electrocatalytic>2Mn, Fe2Co–PCN–Fe2Co, and isolated Fe2M clusters, the mixed-metalFurthermore, the analysis of the electron structure indicates that constructing a mixed-metal clusterIn conclusion, the mixed-metal cluster strategy provides a new approach to further design and synthesize

Keywords： bimetallic metal–organic frameworks     bifunctional electrocatalyst     density functional theory     oxygen    

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Title Author Date Type Operation

Hollow carbon spheres and their noble metal-free hybrids in catalysis

Journal Article

Copper nanoparticles/polyaniline-derived mesoporous carbon electrocatalysts for hydrazine oxidation

Tao Zhang, Tewodros Asefa

Journal Article

Recent advances on metal-free graphene-based catalysts for the production of industrial chemicals

Zhiyong Wang, Yuan Pu, Dan Wang, Jie-Xin Wang, Jian-Feng Chen

Journal Article

Metal-free, carbon-based catalysts for oxygen reduction reactions

Zhiyi Wu,Zafar Iqbal,Xianqin Wang

Journal Article

Noble-metal-free cobalt hydroxide nanosheets for efficient electrocatalytic oxidation

Jie Lan, Daizong Qi, Jie Song, Peng Liu, Yi Liu, Yun-Xiang Pan

Journal Article

Nitrogen-Doped Graphene Foam as a Metal-Free Catalyst for Reduction Reactions under a High Gravity Field

Zhiyong Wang, Zhijian Zhao, Jesse Baucom, Dan Wang, Liming Dai, Jian-Feng Chen

Journal Article

Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study

Journal Article

Shape/size controlling syntheses, properties and applications of two-dimensional noble metal nanocrystals

Baozhen An,Mingjie Li,Jialin Wang,Chaoxu Li

Journal Article

Catalytic activity of noble metal nanoparticles toward hydrodechlorination: influence of catalyst electronic

Man ZHANG,Feng HE,Dongye ZHAO

Journal Article

Metal-Free Hexagonal Perovskite High-Energetic Materials with NH3OH+/NH2

Yu Shang, Zhi-Hong Yu, Rui-Kang Huang, Shao-Li Chen, De-Xuan Liu, Xiao-Xian Chen, Wei-Xiong Zhang, Xiao-Ming Chen

Journal Article

Sulfur-deficient CoNi2S4 nanoparticles-anchored porous carbon nanofibers as bifunctional electrocatalyst

Journal Article

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Journal Article

Zinc modification of Ni-Ti as efficient NiZnTi catalysts with both geometric and electronic improvements for hydrogenation of nitroaromatics

Journal Article

Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells

Gang WU

Journal Article

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reduction and oxygen evolution reaction: a density functional theory study

Journal Article